Atomic Radii
Atomic Radius of Chromium The atomic radius of Chromium atom is 139pm (covalent radius). How atomic radius is defined, and trends across a period and down a group. If you're seeing this message, it means we're having trouble loading external resources on our website. If you're behind a web filter, please make sure that the domains.kastatic.org and.kasandbox.org are unblocked. In specifying values for the radius of an atom, one must keep in mind the fact that atoms are not hard spheres, and the electron distribution in the outer part of the atom does not have a sharp cutoff radius. You could characterize the radius of the atom as a limiting radius where a certain percentage of the electron charge will. Atomic radius, half the distance between the nuclei of identical neighbouring atoms in the solid form of an element. An atom has no rigid spherical boundary, but it may be thought of as a tiny, dense positive nucleus surrounded by a diffuse negative cloud of electrons. The value of atomic radii.
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- Atomic Radius Definition, Trend, And Atomic Radius Periodic ...
- Atomic Radii Of Elements
- Lithium
Periodic Trends — Atomic and Ionic Radii
1A | 2A | 3A | 4A | 5A | 6A | 7A | 8A | |||||||||||
(1) | (2) | (13) | (14) | (15) | (16) | (17) | (18) | |||||||||||
3B | 4B | 5B | 6B | 7B | — | 8B | — | 1B | 2B | |||||||||
(3) | (4) | (5) | (6) | (7) | (8) | (9) | (10) | (11) | (12) | |||||||||
1 | H 78 | He 32 | ||||||||||||||||
2 | Li 152 | Be 113 | B 83 | C 77 | N 71 | O 73 | F 71 | Ne 70 | ||||||||||
3 | Na 186 | Mg 160 | Al 143 | Si 117 | P 115 | S 104 | Cl 99 | Ar 98 | ||||||||||
4 | K 227 | Ca 197 | Sc 161 | Ti 145 | V 132 | Cr 125 | Mn 124 | Fe 124 | Co 125 | Ni 125 | Cu 128 | Zn 133 | Ga 122 | Ge 123 | As 125 | Se 117 | Br 114 | Kr 112 |
5 | Rb 248 | Sr 215 | Y 181 | Zr 160 | Nb 143 | Mo 136 | Tc 136 | Ru 134 | Rh 134 | Pd 138 | Ag 144 | Cd 149 | In 163 | Sn 141 | Sb 141 | Te 143 | I 133 | Xe 130 |
6 | Cs 265 | Ba 217 | La 188 | Hf 156 | Ta 143 | W 137 | Re 137 | Os 135 | Ir 136 | Pt 138 | Au 144 | Hg 160 | Tl 170 | Pb 175 | Bi 155 | Po 167 | At n.a. | Rn 145 |
7 | Fr 270 | Ra 223 | Ac 188 | Rf 150 | Db 139 | Sg 132 | Bh 128 | Hs 126 | Mt n.a. | Ds n.a. | Rg n.a. | Uub n.a. | — | Uuq n.a. | — | — | — | — |
6 | Ce 182 | Pr 183 | Nd 182 | Pm 181 | Sm 180 | Eu 185 | Gd 180 | Tb 178 | Dy 177 | Ho 177 | Er 176 | Tm 175 | Yb 170 | Lu 173 | ||||
7 | Th 180 | Pa 161 | U 154 | Np 150 | Pu 175 | Am 173 | Cm 174 | Bk 170 | Cf 169 | Es 203 | Fm n.a. | Md n.a. | No n.a. | Lr n.a. |
Atomic radii reported in units of picometers (pm).
Data taken from John Emsley, The Elements, 3rd edition. Oxford: Clarendon Press, 1998.
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The atomic radius is the distance from the nucleus of an atom to the outermost electrons. Since the orbitals around an atom are defined in terms of a probability distribution in quantum mechanics, and do not have fixed boundaries, determining where an atom 'stops' is not very straightforward. By comparing the bond lengths of a number of representative compounds of an element, an average size for most atoms can be determined.
The atomic radius can also be defined in other ways. The van der Waals radius (also known as the nonbonding atomic radius) is the radius of an atom which is not bonded to other atoms; this is determined by measuring the distance between atomic nuclei which are in direct but nonbonding contact with each other in a crystal lattice. The covalent atomic radius (also known as the bonding atomic radius) is determined for metals by taking one-half of the distance between two adjacent atoms in a metallic crystal, or one-half the distance between like bonded atoms for nonmetals.
Unfortunately, it is not possible to determine the radius for every element on the periodic table in the same way, and consequently, it is sometimes difficult to make comparisons between different sets of data. In the table above, most of the atomic radii listed are average atomic radii, while for the halogens (Group 7A) and the noble gases (Group 8A) the covalent radius is used.
Atomic radii vary in a predictable way across the periodic table. As can be seen in the figures below, the atomic radius increases from top to bottom in a group, and decreases from left to right across a period. Thus, helium is the smallest element, and francium is the largest.
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- From top to bottom in a group, orbitals corresponding to higher values of the principal quantum number (n) are being added, which are on average further away from the nucleus, thus causing the size of the atom to increase.
- From left to right across a period, more protons are being added to the nucleus, but the electrons which are being added are being added to the valence shell, not to the lower energy levels. As more protons are added to the nucleus, the electrons in the valence shell feel a higher effective nuclear charge — the sum of the charges on the protons in the nucleus and the charges on the inner, core electrons. (See figure below.) The valence electrons are therefore held more tightly, and the size of the atom contracts across a period.
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The following charts illustrate the general trends in the radii of atoms:
The sizes of cations and anions follow similar trends to those of neutral atoms. In general, anions are larger than the corresponding neutral atom, since adding electrons increases the number of electron-electron repulsion interactions that take place. Cations are smaller than the corresponding neutral atoms, since the valence electrons, which are furthest away from the nucleus, are lost. Taking more electrons away from the cation further reduces the radius of the ion.
The table below illustrates these trends for the main group elements. For elements which form more than one cation, the cation charges and sizes are listed in two separate columns. The transition metals and inner transition metals have been omitted, since almost all of those elements can form two or more possible cations.
Sizes of Common Cations and Anions of the Main Group Elements
Atomic Number | Name | Neutral Atom (ppm) | Cation1 Charge | Cation1 Radius (ppm) | Cation2 Charge | Cation2 Radius (ppm) | Anion Charge | Anion Radius (ppm) |
1 | Hydrogen | 78 | 1+ | 0.00066 | 1- | 154 | ||
2 | Helium | 32 | ||||||
3 | Lithium | 152 | 1+ | 78 | ||||
4 | Beryllium | 113 | 2+ | 34 | ||||
5 | Boron | 83 | 3+ | 23 | ||||
6 | Carbon | 77 | 4- | 260 | ||||
7 | Nitrogen | 71 | 3- | 171 | ||||
8 | Oxygen | 73 | 2- | 132 | ||||
9 | Fluorine | 71 | 1- | 133 | ||||
10 | Neon | 70 | ||||||
11 | Sodium | 186 | 1+ | 98 | ||||
12 | Magnesium | 160 | 2+ | 79 | ||||
13 | Aluminum | 143 | 3+ | 57 | ||||
14 | Silicon | 117 | 4+ | 26 | 4- | 271 | ||
15 | Phosphorus | 115 | 3- | 212 | ||||
16 | Sulfur | 104 | 2- | 184 | ||||
17 | Chlorine | 99 | 1- | 181 | ||||
18 | Argon | 98 | ||||||
19 | Potassium | 227 | 1+ | 133 | ||||
20 | Calcium | 197 | 2+ | 106 | ||||
31 | Gallium | 122 | 3+ | 62 | 1+ | 113 | ||
32 | Germanium | 123 | 2+ | 90 | 4- | 272 | ||
33 | Arsenic | 125 | 5+ | 46 | 3+ | 69 | 3- | 222 |
34 | Selenium | 117 | 4+ | 69 | 2- | 191 | ||
35 | Bromine | 114 | 1- | 195 | ||||
36 | Krypton | 112 | ||||||
37 | Rubidium | 248 | 1+ | 149 | ||||
38 | Strontium | 215 | 2+ | 127 | ||||
49 | Indium | 163 | 3+ | 92 | 1+ | 132 | ||
50 | Tin | 141 | 4+ | 74 | 2+ | 93 | 4- | 294 |
51 | Antimony | 141 | 5+ | 62 | 3+ | 89 | 3- | 245 |
52 | Tellurium | 143 | 6+ | 56 | 4+ | 97 | 2- | 211 |
53 | Iodine | 133 | 1- | 196 | ||||
54 | Xenon | 130 | ||||||
55 | Cesium | 265 | 1+ | 165 | ||||
56 | Barium | 217 | 2+ | 143 | ||||
81 | Thallium | 170 | 3+ | 105 | 1+ | 149 | ||
82 | Lead | 175 | 4+ | 84 | 2+ | 132 | ||
83 | Bismuth | 155 | 5+ | 74 | 3+ | 96 | ||
84 | Polonium | 167 | 4+ | 65 | 2- | 230 | ||
85 | Astatine | 5+ | 57 | 1- | 227 | |||
86 | Radon | 145 | ||||||
87 | Francium | 270 | 1+ | 180 | ||||
88 | Radium | 223 | 2+ | 152 |
Atomic Radius Definition, Trend, And Atomic Radius Periodic ...
Atomic Radii Of Elements
Data taken from John Emsley, The Elements, 3rd edition. Oxford: Clarendon Press, 1998.
Lithium
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